Alternative transportation fuels, preferably from renewable sources, include alcohols with up to five or even more carbon atoms. They are considered promising because they can be derived from biological matter via established and new processes. In addition, many of their physical-chemical properties are compatible with the requirements of modern engines, which make them attractive either as replacements for fossil fuels or as fuel additives. Indeed, alcohol fuels have been used since the early years of automobile production, particularly in Brazil, fundamental of analytical chemistry pdf ch 38 ethanol has a long history of use as an automobile fuel.
Today, the ethanol fuel that is offered in the market is mainly made from sugar cane or corn. Its production as a first-generation biofuel, especially in North America, has been associated with publicly discussed drawbacks, such as reduction in the food supply, need for fertilization, extensive water usage, and other ecological concerns. More environmentally friendly processes are being considered to produce alcohols from inedible plants or plant parts on wasteland. Besides ethanol, many linear and branched members of the alcohol family, from methanol to hexanols, have been studied, with a particular emphasis on butanols. These fuels and their combustion properties, including their ignition, flame propagation, and extinction characteristics, their pyrolysis and oxidation reactions, and their potential to produce pollutant emissions have been intensively investigated in dedicated experiments on the laboratory and the engine scale, also emphasizing advanced engine concepts. Research results addressing combustion reaction mechanisms have been reported based on results from pyrolysis and oxidation reactors, shock tubes, rapid compression machines, and research engines. This work is complemented by the development of detailed combustion models with the support of chemical kinetics and quantum chemistry.
This paper seeks to provide an introduction to and overview of recent results on alcohol combustion by highlighting pertinent aspects of this rich and rapidly increasing body of information. As such, this paper provides an initial source of references and guidance regarding the present status of combustion experiments on alcohols and models of alcohol combustion. Check if you have access through your login credentials or your institution. In the scope of its subject, chemistry occupies an intermediate position between physics and biology. The history of chemistry spans a period from very old times to the present.
Since several millennia BC, civilizations were using technologies that would eventually form the basis of the various branches of chemistry. It was unsuccessful in explaining the nature of matter and its transformations, but, by performing experiments and recording the results, alchemists set the stage for modern chemistry. In origin, the term is borrowed from the Greek χημία or χημεία. The basis of such a chemical transformation is the rearrangement of electrons in the chemical bonds between atoms. The number of atoms on the left and the right in the equation for a chemical transformation is equal. The type of chemical reactions a substance may undergo and the energy changes that may accompany it are constrained by certain basic rules, known as chemical laws. Most chemists specialize in one or more sub-disciplines.
The atom is the basic unit of chemistry. In a neutral atom, the negatively charged electrons balance out the positive charge of the protons. 1,836 times that of an electron, yet the radius of an atom is about 10,000 times that of its nucleus. The properties of a compound bear little similarity to those of its elements. When a compound has more than one component, then they are divided into two classes, the electropositive and the electronegative components.